Class 5 Oxidizing Substances

Oxidizers are materials that can provide oxygen or increase the oxygen content in the air, making other materials more susceptible to burning or combusting.

Organic peroxides, as you mentioned, are a specific type of oxidizer that are derived from hydrogen peroxide, where one or both of the hydrogen atoms have been replaced with an organic group. Organic peroxides are particularly dangerous because they are highly reactive and can easily decompose, releasing heat and potentially leading to a fire or explosion.

Sub-Division

Division 5.1: Oxidizing substances
Division 5.2: Organic peroxides

Reason for Regulation

Oxidizers are not necessarily combustible materials themselves, but they can provide oxygen or increase the oxygen content in the air, making other materials more susceptible to burning or combusting. This can make it difficult to control a fire once it starts and can lead to an acceleration of the fire and an increase in the heat release rate, which can be extremely dangerous.

Commonly Transported Oxidizers; Organic Peroxides

  1. Chemical oxygen generators
  2. Ammonium nitrate fertilizers
  3. Chlorates
  4. Nitrates
  5. Nitrites
  6. Perchlorates
  7. Permanganates
  8. Persulphates
  9. Aluminium nitrate
  10. Ammonium dichromate
  11. Ammonium nitrate
  12. Ammonium persulphate
  13. Calcium hypochlorite
  14. Calcium nitrate
  15. Calcium peroxide
  16. Hydrogen peroxide
  17. Magnesium peroxide
  18. Lead nitrate
  19. Lithium hypochlorite
  20. Potassium chlorate
  21. Potassium nitrate
  22. Potassium chlorate
  23. Potassium perchlorate
  24. Potassium permanganate
  25. Sodium nitrate
  26. Sodium persulphate.
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